# Thermodynamics — AP Physics 2
Thermodynamics connects heat, work, and energy at the macroscopic level. AP Physics 2 covers the ideal gas law, the laws of thermodynamics, PV diagrams, and heat engines. Mastering these topics requires understanding both the mathematical relationships and the conceptual meaning of each process.
Key Concepts
Temperature and Thermal Energy
- Temperature: measure of average kinetic energy of particles.
- Average KE per molecule: (for ideal monatomic gas).
- .
Ideal Gas Law
where = moles, , = number of molecules.
First Law of Thermodynamics
- : change in internal energy
- : heat added to the system (positive = heat in)
- : work done by the system (positive = expansion)
Thermodynamic Processes
| Process | Constant | Consequence |
|---|---|---|
| Isothermal | , | |
| Isobaric | ||
| Isochoric (Isovolumetric) | , | |
| Adiabatic |
PV Diagrams
- Work done by gas = area under the curve on a PV diagram.
- Clockwise cycle: net positive work (heat engine).
- Counterclockwise cycle: net negative work (refrigerator).
Second Law of Thermodynamics
- Heat flows spontaneously from hot to cold.
- Entropy of an isolated system never decreases.
- No heat engine can be 100% efficient.
Heat Engine Efficiency
Carnot (maximum) efficiency:
Worked Example
Problem: An ideal gas in a sealed container () at and is heated to at constant volume. What is the final pressure?
Solution:
At constant volume:
Practice Questions
1. How much work does a gas do when it expands from to at a constant pressure of ?
.
2. A gas absorbs of heat and does of work. What is ?
.
3. A heat engine operates between and . What is its maximum efficiency?
.
4. During an adiabatic expansion, what happens to the temperature of an ideal gas?
It decreases. Since , the gas does work at the expense of internal energy, so and temperature drops.
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Summary
- The ideal gas law () describes gas behavior.
- First law: — energy is conserved.
- PV diagram area = work done by the gas.
- Carnot efficiency sets the upper limit for heat engines.
