Quantum, Atomic & Nuclear Physics

AP Physics 2 review of quantum physics, the photoelectric effect, atomic models, energy levels, nuclear physics, and radioactive decay.

# Quantum, Atomic & Nuclear Physics — AP Physics 2

Modern physics revolutionized our understanding of nature at the atomic and subatomic level. AP Physics 2 covers the photoelectric effect, wave-particle duality, atomic energy levels, nuclear structure, and radioactive decay.

Key Concepts

The Photoelectric Effect

Light ejects electrons from a metal surface. Ephoton=hf=hcλE_{\text{photon}} = hf = \frac{hc}{\lambda} where h=6.63×1034 J\cdotpsh = 6.63 \times 10^{-34}\ \text{J·s}.

KEmax=hfϕKE_{\max} = hf - \phi where ϕ\phi is the work function (minimum energy to eject an electron).

  • Below the threshold frequency (f0=ϕ/hf_0 = \phi/h), no electrons are emitted regardless of intensity.
  • Increasing intensity increases the number of electrons, not their maximum KE.

Wave-Particle Duality

  • Light behaves as both a wave and a particle (photon).
  • de Broglie wavelength of a particle: λ=h/p=h/(mv)\lambda = h/p = h/(mv).

Atomic Models

Bohr Model (Hydrogen):

  • Electrons occupy discrete energy levels.
  • Energy levels: En=13.6 eVn2E_n = -\frac{13.6\ \text{eV}}{n^2}
  • Photon emitted/absorbed when electron transitions: Ephoton=EfEiE_{\text{photon}} = |E_f - E_i|

Emission and Absorption Spectra

  • Emission spectrum: bright lines on dark background (excited atoms emit specific wavelengths).
  • Absorption spectrum: dark lines on continuous background (atoms absorb specific wavelengths).

Nuclear Structure

  • Atomic number (ZZ): number of protons.
  • Mass number (AA): protons + neutrons.
  • Isotopes: same ZZ, different AA.

Nuclear Reactions and Conservation Laws

  • Conservation of: charge, nucleon number (baryon number), energy, momentum.

Radioactive Decay

Type Particle ZZ Change AA Change
Alpha (α\alpha) 24He^4_2\text{He} 2-2 4-4
Beta minus (β\beta^-) ee^- +1+1 00
Beta plus (β+\beta^+) e+e^+ 1-1 00
Gamma (γ\gamma) photon 00 00

Half-Life

N=N0(12)t/t1/2N = N_0 \left(\frac{1}{2}\right)^{t/t_{1/2}}

Mass-Energy Equivalence

E=mc2E = mc^2

Mass defect: the mass of a nucleus is less than the sum of its parts. The "missing" mass is the binding energy.

Worked Example

Problem: UV light with wavelength 200 nm200\ \text{nm} strikes a metal with work function ϕ=4.0 eV\phi = 4.0\ \text{eV}. What is the maximum kinetic energy of the ejected electrons?

Solution:

Ephoton=hc/λ=(6.63×1034)(3×108)/(200×109)=9.945×1019 JE_{\text{photon}} = hc/\lambda = (6.63 \times 10^{-34})(3 \times 10^8)/(200 \times 10^{-9}) = 9.945 \times 10^{-19}\ \text{J}

Convert to eV: 9.945×1019/1.6×1019=6.22 eV9.945 \times 10^{-19} / 1.6 \times 10^{-19} = 6.22\ \text{eV}

KEmax=6.224.0=2.22 eVKE_{\max} = 6.22 - 4.0 = 2.22\ \text{eV}

Practice Questions

  1. 1. What is the energy of a photon with frequency 5×1014 Hz5 \times 10^{14}\ \text{Hz}?

    E=hf=(6.63×1034)(5×1014)=3.315×1019 J2.07 eVE = hf = (6.63 \times 10^{-34})(5 \times 10^{14}) = 3.315 \times 10^{-19}\ \text{J} \approx 2.07\ \text{eV}.

    2. An electron in hydrogen transitions from n=3n = 3 to n=1n = 1. What is the photon energy?

    E=E1E3=13.6(1.51)=12.09 eVE = |E_1 - E_3| = |-13.6 - (-1.51)| = 12.09\ \text{eV}.

    3. Uranium-238 undergoes alpha decay. Write the reaction and identify the daughter nucleus.

    92238U90234Th+24He^{238}_{92}\text{U} \rightarrow ^{234}_{90}\text{Th} + ^{4}_{2}\text{He}. Daughter: Thorium-234.

    4. A sample has a half-life of 10 days10\ \text{days}. After 30 days30\ \text{days}, what fraction remains?

    (1/2)30/10=(1/2)3=1/8(1/2)^{30/10} = (1/2)^3 = 1/8.

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Summary

  • Photoelectric effect: KEmax=hfϕKE_{\max} = hf - \phi; threshold frequency exists.
  • Bohr model: discrete energy levels, En=13.6/n2E_n = -13.6/n^2 eV for hydrogen.
  • Nuclear decay conserves charge and nucleon number; half-life governs decay rate.
  • E=mc2E = mc^2 connects mass and energy; mass defect gives binding energy.

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